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N. B. Tamm, L. N. Sidorov, S. I. Troyanov

Investigations in the field of higher fullerenes

Abstract

Halogenation of higher fullerene mixtures or their perfluoroalkylation with RFI followed by HPLC separation of RF derivatives and subsequent synchrotron X-ray crystallographic study allowed one to confirm cage connectivities of higher fullerenes and, in addition, to receive information concerning their reactivity in radical addition reactions. The data obtained are compared with theoretical predictions for higher fullerenes. Addition patterns of higher fullerene derivatives are discussed. Skeletal rearrangement of D2–C76 cage during chlorination has been observed for the first time.
Moscow University Chemistry Bulletin.
2009, Vol. 50, No. 6, P. 411
   

Copyright (C) Chemistry Dept., Moscow State University, 2002
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