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E. M. Basova, V. M. Ivanov, O. K. Apendeeva, G. V. Prokhorova
Study of oxidation diethyldithiocarbamate
of sodium on glassy carbon electrode in water and water-organic solutions
Abstract
The oxidation of diethyldithiocarbamate of
sodium on glassy carbon electrode in water and water-organic solutions on a
background KCI and NaOH is investigated. By methods cyclic, square-wave
voltammetry and voltammetry on a rotating electrode is shown, that in water and
in water-organic solutions the electrode reaction is irreversible. The
oxidation in a water solution KCI proceeds with participation one electron and
in water-organic solution KCI with participation two electrons. The possible
mechanism of oxidation is discussed.
Key words: diethyldithiocarbamate of
sodium, voltammetry, glassy carbon electrode, oxidation.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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